Abstract: | Experimental and theoretical studies of the optical birefringence increment in the transition and metastable states of the
incommensurate phase of Rb2ZnBr4, N(CH3)4]2MeCl4 (Me = Zn, Cu, Fe) crystals have been made. It has been established that in the modulated structure field a defect density
wave is formed. It has been shown that when the period of the defect density wave coincides with the period of the modulation
wave, the region of existence of the metastable state expands; when the periods of these waves do not coincide, their superposition
occurs, with the formation of a wave with a difference value of the modulation vector. The presence of defect density waves
in the incommensurate phase leads to a temperature hysteresis and kinetics of the physical quantities in the vicinity of Tc.
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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 72, No. 5, pp. 632–639, September–October, 2005. |