Dissolution of Ca3(AsO4)2 · 2H2O in the system CaOAs2O5H2O at 35, 40, 45 and 50°C and the related thermodynamic data |
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Authors: | PP Mahapatra LM Mahapatra CN Nanda |
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Institution: | Post-Graduate Department of Chemistry, Khallikote College, Berhampur, GM 760 001 India |
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Abstract: | Calcium arsenate dihydrate is precipitated at pH 7.0 and its dissolution in aqueous solutions at temperatures of 35, 40, 45 and 50°C and a pH of between 3.0 and 8.0 is investigated. The thermodynamic parameters ΔG0, ΔS0 and ΔH0 for the process are evaluated. Temperature dependence of solubility is obtained by the equations ?log KTCA = ? 34.0468 + 0.0821421 T |
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Keywords: | Author for correspondence at the present address: Department of Chemistry Science College Chatrapur GM 761 020 India |
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