Palladium-catalyzed cross-coupling of indium homoenolate with aryl halide with wide functional group compatibility |
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| Authors: | Shen Zhi-Liang Lai Yin-Chang Wong Colin Hong An Goh Kelvin Kau Kiat Yang Yong-Sheng Cheong Hao-Lun Loh Teck-Peng |
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| Institution: | Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371. |
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| Abstract: | An efficient palladium-catalyzed cross-coupling of indium homoenolate with aryl halide is described. The reactions proceeded efficiently in DMA at 100 °C to afford the desired products of β-aryl ketones in moderate to good yields. Various important functional groups including COR, COOR, CHO, CN, OH, and NO(2) can be well tolerated in the protocol. |
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