| 一维链状配位聚合物[Ag(bix)(NO3)(H2O)]n的合成和晶体结构 |
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| 引用本文： | 吴燕萍,温丽丽,李一志,党东宾,鲁振达,孟庆金. 一维链状配位聚合物[Ag(bix)(NO3)(H2O)]n的合成和晶体结构[J]. 无机化学学报, 2005, 21(11): 1759-1762 |
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| 作者姓名： | 吴燕萍 温丽丽 李一志 党东宾 鲁振达 孟庆金 |
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| 作者单位： | 南京大学配位化学研究所,配位化学国家重点实验室,南京,210093 |
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| 基金项目： | 国家自然科学基金资助项目(No.20490218)。 |
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| 摘 要： | A one-dimensional (1D) Z conformation coordination polymer, [Ag(bix)(NO3)(H2O)]n was obtained by the reaction between AgNO3 and flexible ligand of 1,4-bis(imidazol-1-ylmethyl)-benzene under hydrothermal conditions. It crystallizes in triclinic with space group P1. The crystallographic data of the compound are: a=0.777 1(2) nm, b=1.043 4(3) nm, c=1.082 7(3) nm, α=71.403(4)°, β=80.946(5)°, γ=88.794(4)°. The 1D chainlike structure was connected by π-π interaction between phenyl rings, leading to a 2D layered network. The lattice water and the NO3- anions were involved between the layers, therefore the 2D layered structure further extended to an intricate 3D framework. CCDC: 257100.
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| 关 键 词： | 银(Ⅰ)配合物； 晶体结构； 配位聚合物 |
| 文章编号： | 1001-4861(2005)11-1759-04 |
| 收稿时间： | 2005-04-05 |
| 修稿时间： | 2005-09-01 |
Synthesis and Crystal Structure of One-Dimensional Chainlike Coordination Polymer [Ag(bix)(NO3)(H2O)]n |
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| WU Yan-Ping,WEN Li-Li,LI Yi-Zhi,DANG Dong-Bin,LU Zhen-Da and MENG Qing-Jin. Synthesis and Crystal Structure of One-Dimensional Chainlike Coordination Polymer [Ag(bix)(NO3)(H2O)]n[J]. Chinese Journal of Inorganic Chemistry, 2005, 21(11): 1759-1762 |
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| Authors: | WU Yan-Ping WEN Li-Li LI Yi-Zhi DANG Dong-Bin LU Zhen-Da MENG Qing-Jin |
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| Affiliation: | Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 and Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 |
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