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| 含偶氮苯聚芳亚胺的合成、表征和光谱分析 | |
| 引用本文： | 罗炫,常冠军,焦文秀,张林,林润雄.含偶氮苯聚芳亚胺的合成、表征和光谱分析[J].化学研究,2009,20(2):48-51. |
| 作者姓名： | 罗炫 常冠军 焦文秀 张林 林润雄 |
| 作者单位： | 1. 中国工程物理研究院,激光聚变中心,四川,绵阳,621900 2. 中国工程物理研究院,激光聚变中心,四川,绵阳,621900;青岛科技大学,橡塑材料与工程教育部重点实验室,山东,青岛,266042 3. 青岛科技大学,橡塑材料与工程教育部重点实验室,山东,青岛,266042 |
| 基金项目： | 国家自然科学联合基金，中国工程物理研究院科学技术发展基金，高温高密度等离子体物理国防科技重点实验室基金 |
| 摘 要： | 以4，4＇-二溴二苯甲酮和4，4＇-二氨基偶氮苯为单体，通过钯催化的胺基化反应缩聚合成了含偶氮苯基团的新型结构聚芳亚胺（PAI-A）．PAI-A结构通过FT—IR，^1H NMR和元素分析测定，测试结果和目标产物吻合良好．在不同的条件下测定了聚合物的光学性能． |
| 关 键 词： | 聚芳亚胺 偶氮苯 钯催化 胺化 |
Synthesis,Characterization and Spectra of Poly(arylimine) Containing Azobenzene Group |
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| LUO Xuan,CHANG Guan-jun,JIAO Wen-xiu,ZHANG Lin,LIN Run-xiong.Synthesis,Characterization and Spectra of Poly(arylimine) Containing Azobenzene Group[J].Chemical Research,2009,20(2):48-51. | |
| Authors: | LUO Xuan CHANG Guan-jun JIAO Wen-xiu ZHANG Lin LIN Run-xiong |
| Institution: | LUO Xuan, CHANG Guan-jun, JIAO Wen-xiu, ZHANG Lin, LIN Run-xiong( 1. Research Center of Laser Fusion, China Academy of Engineering Physics, Mianyang 621900, Sichuan, China; 2. Key Laboratory of Rubber-plastics, Ministry of Education, Qingdao University of Science and Technology, Qingdao 266042, Shandong, China) |
| Abstract: | With 4,4′-dibromobenzophenone and 4,4′-diaminoazobenzene as monomers, poly(arylimine) containing azobenzene unite (PAI-A) was synthesized via palladium-catalyzed amination. The structure of PAI-A was characterized by means of FT-IR, 1H NMR and elemental analysis, the result shows an agreement with the proposed structure. The UV absorption apectra were tested under different conditions. |
| Keywords: | poly(aryl imine) azobenzene palladium-catalysis amination |
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