| RbFeCl3晶体的光磁性理论研究 |
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| 引用本文： | 刘芳玲,廖显威.RbFeCl3晶体的光磁性理论研究[J].西南民族学院学报(自然科学版),1997,23(4):377-379. |
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| 作者姓名： | 刘芳玲 廖显威 |
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| 作者单位： | 四川师范大学化学系 |
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| 摘 要： | 在Ｄ３ｄ晶场下利用Ｏｈ点群表象方法，构造了ｄ６电子系的完全能量矩阵．使用全组态相互作用方法计算了ＲｂＦｅＣｌ３晶体中Ｆｅ２＋的电子光谱和零场分裂因子，其计算结果与观测数据一致．
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| 关 键 词： | 能量矩阵，d－d跃迁，零场分裂因子 |
A Theoretical Study of Optical Spectrum and Magnetic Properties RbFeCl 3 Crystal |
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| Liu,Fangling,Liao,Xianwei.A Theoretical Study of Optical Spectrum and Magnetic Properties RbFeCl 3 Crystal[J].Journal of Southwest Nationalities College(Natural Science Edition),1997,23(4):377-379. |
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| Authors: | Liu Fangling Liao Xianwei |
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| Abstract: | The total energy matrices of d 6 eletronic system in the D 3d point group are given by using an O h point group representation.The d-d transition of the Fe 2 ions in RbFeCl 3 crystal are explained and the zero field splitting is derived with the full configuration and iaceraction method.The calculated results are in agreement with observed values. |
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| Keywords: | energy matrices d d transition zero fild splitting |
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