Synthesis and studies of new plasticized PVP: NaClO3 electrolyte system for battery applications |
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| Authors: | R. Sathiyamoorthi R. Chandrasekaran S. Selladurai T. Vasudevan |
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| Affiliation: | (1) Department of Physics, Solid State Ionics Lab, MIT, Anna University, 600 044 Chennai, India;(2) Department of Industrial Chemistry, Alagappa University, 630 003 Karaikudi, India;(3) SF-32,MGR Street, Pallavan Nagar (TNHB), 631 501 Kanchipuram, Tamil Nadu, India |
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| Abstract: | A new thin film sodium ion conducting plasticized polymer electrolyte based on poly(vinyl pyrrolidone) (PVP) complexed with NaClO3 salt systems was prepared by the solution-cast method. The interaction of NaClO3 salt with PVP was confirmed by Infrared (IR) study. Charge transport of these polymer electrolytes is due to ions, which was confirmed by Wagner’s polarization method. From the conductivity measurements, the highest conductivity value 6.71×10−5 S/cm was observed for the composition PVP:PEG:NaClO3(30:60:10) at room temperature 35 °C. The redox behaviour and good reversibility of the plasiticized electrolytes are confirmed by electrochemical techniques. Electrochemical cell studies of these polymer electrolytes were analyzed from their discharge characteristics. The open-circuit voltage (OCV) and short-circuit current (SCC) were found to in the range of 2.52 V to 2.36 V and 760 μA to 1040 μA, respectively. |
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