Formation of stable radicals during the reduction of fluoranil in alkaline alcoholic solutions |
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Authors: | R. I. Samoilova A. D. Milov Yu. D. Tsvetkov |
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Affiliation: | (1) Institute of Chemical Kinetics and Combustion, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk |
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Abstract: | The magnetic-resonance parameters of a stable radical formed under anaerobic conditions during the reduction of fluoranil in alkaline alcohols were measured by the EPR, ENDOR and electron spin echo methods. It was concluded that a tetraethoxy-p-benzoquinone anion-radical is formed.Translated from Teoreticheskaya i Eksperimental'naya Khimiya, Vol. 26, No. 2, pp. 249–251, March–April, 1990.The authors wish to express their gratitude of I. I. Bil'kis for his participation in the discussions of the results of this work. |
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