Invertible amphiphilic homopolymers |
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Authors: | Basu Subhadeep Vutukuri Dharma Rao Shyamroy Subarana Sandanaraj Britto S Thayumanavan S |
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Institution: | Department of Chemistry, University of Massachusetts, Amherst, Massachusetts 01003, USA. |
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Abstract: | Stimuli-responsive polymers and assemblies are viable candidates for the so-called "smart" materials. In this communication, we report a new class of amphiphilic homopolymers that forms micelle-like structures in polar solvents and inverted micelle-like structures in apolar solvents. We demonstrate that these superstructures are the result of the changes in the molecular-level conformations in the monomer. |
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