Oxidative heck-type reaction involving cleavage of a carbon-phosphorus bond of arylphosphonic acids |
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| Authors: | Inoue Atsushi Shinokubo Hiroshi Oshima Koichiro |
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| Affiliation: | Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 606-8501, Japan. |
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| Abstract: | Cleavage of a carbon-phosphorus bond is achieved under palladium catalysis in an oxidative Heck-type reaction which exploits arylphosphonic acids. The reaction of arylphosphonic acids with alkenes provides arylation products in good yields in the presence of TBAF with trimethylamine oxide as an oxidant. |
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