Unusual pathway of alkylation of 2-(4-bromobenzylidene)-<Emphasis Type="Italic">p</Emphasis>-menthan-3-one with ethyl bromoacetate |
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| Authors: | A I Krivoshei S V Shishkina V V Vashchenko O V Shishkin |
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| Institution: | (1) Scientific Technological Institution “Institute for Single Crystals”, National Academy of Sciences of Ukraine, 60 prosp. Lenina, 61001 Kharkov, Ukraine |
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| Abstract: | Reaction of enolate carbanion, generated from 2-(4-bromobenzylidene)-p-menthan-3-one, with ethyl bromoacetate proceeds selectively as the O-alkylation.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2420–2423, December, 2007. |
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| Keywords: | O-alkylation arylindene-p-menthan-3-one core enolates enol ethers X-ray diffraction analysis |
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