Voltammetric Determination of Tin(II) and Iron(II) on Mechanically Renewed Graphite Electrode in Tin-Plating Electrolyte |
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Authors: | Skvortsova L I Medvedev A Zh |
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Institution: | (1) Institute of Solid-State Chemistry and Mechanochemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia |
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Abstract: | The analytical properties of the cathodic peak of tin(II) reduction and the anodic peak of iron(II) oxidation on a graphite electrode were studied with the electrode surface mechanically renewed directly in a solution before applying a potential in each measurement. The influence of the organic components of the phenolsulfonic tin-plating electrolyte on the cathodic current of tin(II) reduction and anodic current of iron(II) oxidation was studied. A dc voltammetric method was proposed for determining tin(II) directly in the phenolsulfonic tin-plating electrolyte, and iron(II) after the electrolyte is diluted tenfold with a 0.5M H2SO4 supporting solution. |
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