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Circular dichroism of optically active planar chiral cyclopalladium ferrocene derivatives. Investigation of the dimer-monomer equilibrium |
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| Authors: | V. I. Sokolov L. A. Bulygina K. K. Babievskii I. A. Yamskov |
| Affiliation: | (1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991 Moscow, Russian Federation |
| Abstract: | The concentration dependence of the circular dichroism spectra of optically active dinuclear 2-dimethylaminomethylferrocenylpalladium chloride was studied in two solvents. The observed changes in the position and intensity of the Cotton effects were interpreted as a consequence of the dimer-monomer equilibrium. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1411–1413, July, 2007. |
| Keywords: | chelate palladocycle ferrocenes optical activity circular dichroism Cotton effects concentration dependence dimer-monomer equilibrium |
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