Reductive desorption of thiolate from monolayer protected gold clusters |
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| Authors: | Quinn Bernadette M Kontturi Kyösti |
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| Affiliation: | Laboratory of Physical Chemistry and Electrochemistry, Helsinki University of Technology, P.O. Box 6100, FIN-2015 HUT, Finland. bquinn@iki.fi |
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| Abstract: | The "electrochemical potential window" of monolayer-protected gold cluster (MPC) nanoelectrodes is probed where the electrified liquid-liquid interface is used as the detector. The first observation of the reductive desorption of thiolate at negative MPC core charge is reported. |
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