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Palladium(II) Schiff base complexes derived from sulfanilamides and aminobenzothiazoles |
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| Authors: | Robin R Coombs Melissa K Ringer Johanna M Blacquiere Joshua C Smith J Scott Neilsen Yoon-Seo Uh J Bryson Gilbert Lisa J Leger Haiwen Zhang Alison M Irving Susan L Wheaton Christopher M Vogels Stephen A Westcott Andreas Decken Felix J Baerlocher |
| Institution: | (1) Department of Chemistry, Mount Allison University, Sackville, NB, Canada, E4L 1G8;(2) Department of Chemistry, University of New Brunswick, Fredericton, NB, E3B 5A3, Canada;(3) Department of Biology, Mount Allison University, Sackville, NB, Canada, E4L 1G7 |
| Abstract: | Schiff bases (HL) derived from sulfanilamides or aminobenzothiazoles add to Pd(OAc)2 to give complexes of the type PdL2 (1–7) in moderate to excellent yields. Reactions of Schiff bases containing pyrimidine groups, however, gave several products arising from competing coordination of the pyrimidine nitrogen. Palladium complexes and Schiff bases have been investigated as antifungal agents against Aspergillus niger and Aspergillus flavus. |
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