Controlling transformations in the assembly of polyoxometalate clusters: {Mo11V7}, {Mo17V8} and {Mo72V30} |
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| Authors: | Miras Haralampos N Ochoa M Nieves Corella Long De-Liang Cronin Leroy |
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| Affiliation: | WestCHEM, Department of Chemistry, University of Glasgow, Glasgow G12 8QQ, Scotland, UK. |
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| Abstract: | The reaction of molybdate with vanadium(V) in the presence of sulfite anions is explored showing how, via cation control, stepwise assembly through the {Mo(11)V(7)} cluster yields a {M(25)} cluster-based compound, [Mo(VI)(11)V(V)(5)V(IV)(2)O(52)(μ(9)-SO(3))(Mo(VI)(6)V(V)O(22))](10-) (1a), which was first discovered using cryospray mass spectrometry, whereas switching the cation away from ammonium allows the direct formation of the spherical 'Keplerate' {Mo(72)V(30)} cluster. |
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