Selective heterolytic P-P bond cleavage of white phosphorus by a frustrated carbene-borane Lewis pair |
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| Authors: | Holschumacher Dirk Bannenberg Thomas Ibrom Kerstin Daniliuc Constantin G Jones Peter G Tamm Matthias |
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| Institution: | Institut für Anorganische und Analytische Chemie, Technische Universit?t Braunschweig, Hagenring 30, D-38106, Braunschweig, Germany. |
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| Abstract: | Frustrated carbene-borane Lewis pairs are able to affect the selective cleavage of one of the six P-P bonds in white phosphorus (P(4)) to afford an adduct, in which an abnormal carbene of the imidazolium-4-yl type and B(C(6)F(5))(3) are bound in a trans,trans fashion to a butterfly-like bicyclo1.1.0]tetraphosphabutane moiety. |
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