Synthesis of new metallomesogens with enaminoketone chelating ligands |
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| Authors: | V. N. Kovganko N. N. Kovganko |
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| Affiliation: | (1) Sevchenko Institute of Applied Physical Problems, Belarussian State University, ul. Kurchatova 7, Minsk, 220064, Belarus |
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| Abstract: | New liquid crystalline copper(II) enaminoketonates containing bridging ester groups were synthesized by hydrogenation of the heteroring in 3-(4-hydroxyphenyl)-5-pentylisoxazole to 1-amino-1-(4-hydroxyphenyl)oct-1-en-3-one, treatment of the latter with copper(II) acetate, and benzoylation of the coordination compound thus formed with 4-alkoxybenzoyl chlorides. |
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