Small-angle neutron scattering from micelles of alkylpolyoxyethylene sulfate: Effect of chain length |
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Authors: | E Caponetti R Triolo J S Johnson Jr |
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Institution: | (1) Istituto di Chimica Fisica, V. Archirafi 26, 90123 Palermo, Italy;(2) Chemistry Division, Oak Ridge National Laboratory, 37831 Oak Ridge, TN |
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Abstract: | Small-angle neutron scattering (SANS) data have been obtained for (i) a series of solutions of C
m
H2m+1(OCH2–CH2)2SO4Na, for m=18, 16, and 14; (ii) an approximately 0.07M solution of C14H29(OCH2–CH2)2SO4Na to which different amounts of NaCl were added; and (iii) a series of solutions of variable concentration of C12H25(OCH2–CH2)SO4Na. The increase of the number of carbon atoms of the hydrocarbon chain produces a noticeable increase of the aggregation number of the micelles, while the salt tolerance decreases with increasing m. All the data can be described in terms of a monodispersed, charged, hard-spheres model interacting via a screened Coulombic potential, except the run at highest salt concentration, for which an ellipsoid model gives better results. |
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Keywords: | Neutron scattering alkylpolyoxyethylene micelles aggregation number |
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