具有纳米孔洞的金属-有机超分子聚合物与功能材料

本文介绍了近几年来一个热门的研究领域－纳米超分子笼和具有纳米孔洞的金属－有机聚合物的研究现状和发展趋势。目前该领域的研究主要集中在：设计合成有机桥联配体并与金属离子自组装成各类具有纳米孔洞的超分子化合物和一维、二维或三维的金属－有机聚合物，应用结构化学研究手段，研究它们的自组装规律、空间结构、电子结构及其物理化学性能，寻找这两类化合物在生物工程与功能材料等领域中的应用。

Metal-Organic Supramolecular Polymers with Nanometer-Sized Pores and its Application in Functional Materials

This paper presents the status and progress of a recent active research field in the nanometer-sized metallosupramolecular cage and the new type of metal-organic macroporous zeotype. The research of this field are mainly focussed on: (1) design and syntheses of exo-multidentate ligands and preparation of the metallosupramolecular coordination complexes as well as one-, two- and three-dimensional polymers with nanometer-sized pores by self-assembly reaction of metal ions and these ligands; (2) investigation of their assembly roles, geometric structures, electronic structures, and chemical and physical properties; (3) application of these coordination polymers in biological engineering and function materials.