Ni(COD)2/4-ClC6H4COR-catalyzed addition reactions of arylboroxines with aldehydes |
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Authors: | Chun-Hui Xing |
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Institution: | Department of Chemistry, College of Staten Island and the Graduate Center of the City University of New York, 2800 Victory Boulevard, Staten Island, NY 10314, United States |
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Abstract: | Ni(COD)2/4-ClC6H4COR (R = H, CH3, Ph) was found to be an efficient catalyst system for the addition reactions of arylboroxines with aromatic and aliphatic aldehydes. The catalytically active species for Ni(COD)2/4-ClC6H4COR catalyst systems was likely to be their oxidative addition adducts, 4-RCOC6H4Ni(II)Cl(COD) complexes. |
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