The first one-pot ‘alkane-like’ reactions of carbonyl-containing adamantanes |
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| Authors: | Irena Akhrem,Dzhul&rsquo etta Avetisyan,Lyudmila Afanas&rsquo eva,Nikolai Kagramanov,Pavel Petrovskii,Alexander Orlinkov |
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| Affiliation: | A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov Street, Moscow 119991, Russian Federation |
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| Abstract: | A novel ‘alkane-like’ methodology for the direct and very simple one-pot functionalization of amides and an ester of 1-adamantanecarboxylic acid provides access to new and synthetically challenging 1,3-dicarbonyl-containing adamantanoid compounds with the same or different functional groups. |
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| Keywords: | &lsquo Alkane-like&rsquo reactions Synthesis 1,3-Dicarbonyl-containing adamantane Superelectrophiles |
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