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gem-Bromochlorospiropentane reactivity toward methyllithium: an unusual carbenoid rearrangement |
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| Authors: | Kseniya N. Sedenkova Nikolai S. Zefirov |
| Affiliation: | Department of Chemistry, Moscow State University, Leninskie Gory 1/3, 119991 Moscow, Russia Federation |
| Abstract: | A skeletal carbenoid rearrangement of the gem-bromochlorospiropentanes in the presence of methyllithium has been studied. The synthetic and mechanistic aspects of this rearrangement as well as the influence of the halogen atom nature on the reaction pathway are discussed. |
| Keywords: | Carbenoids Methyllithium Spiro compounds Halogenocyclobutenes gem-Dihalogenospiropentanes |
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