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Enantiospecific total synthesis of aciphyllene
Authors:A. Srikrishna  Vijendra H. Pardeshi
Affiliation:Department of Organic Chemistry, Indian Institute of Science, C. V. Raman Avenue, Bangalore, Karnataka 560012, India
Abstract:Enantiospecific total synthesis of the sesquiterpene aciphyllene and its three epimers have been described starting from the readily available monoterpene (R)-limonene employing an intramolecular type II carbonyl ene reaction as the key step.
Keywords:Sesquiterpenes   Aciphyllenes   Limonene   Intramolecular type II carbonyl ene reaction   Enantiospecific synthesis
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