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Synthesis of gigantic macrocyclic polyketones through catalytic cyclometalation of cycloalkynes |
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| Authors: | Vladimir A D’yakonov Aleksey A Makarov Usein M Dzhemilev |
| Institution: | Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 Prospekt Oktyabrya, Ufa, 450075, Russia |
| Abstract: | A new effective method for designing unique gigantic polyfunctional macrocarbocycles from cyclic acetylenes and Grignard reagents through the catalytic cyclometalation reaction in the presence of transition metal based complexes has been elaborated. |
| Keywords: | Cycloalumination Cyclomagnesiation cyclic alkynes Zr complexes Homogeneous catalysis Macrocyclic ketones Ozonolysis |
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