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Montmorillonite clay-catalyzed cyclotrimerization and oxidation of aliphatic aldehydes |
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| Authors: | Matthew R. Dintzner Yawo A. Mondjinou Dominic J. Pileggi |
| Affiliation: | Department of Chemistry, DePaul University, 1110 West Belden Ave., Chicago, IL 60614, United States |
| Abstract: | A temperature-dependent equilibrium is observed for the cyclotrimerization of aliphatic aldehydes in the presence of Montmorillonite K10 clay, while aerobic oxidation of aliphatic aldehydes to the corresponding carboxylic acids is favored at room temperature in the presence of Montmorillonite KSF clay. |
| Keywords: | Cyclotrimerization Aliphatic aldehydes Montmorillonite clay Oxidation Carboxylic acids 1,3,5-Trioxanes Green chemistry |
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