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The first example of stereoselective self-assembly of a cryptand containing four asymmetric intracyclic phosphane groups |
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| Authors: | Roman N Naumov Artem V Kozlov Santiago Gómez-Ruiz Evamarie Hey-Hawkins Andrey A Karasik |
| Institution: | a A.E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Kazan Scientific Center, Arbuzov str. 8, Kazan 420088, Russian Federation b Departamento de Química Inorgánica y Analítica, Universidad Rey Juan Carlos, C/ Tulipán s/n E-28933 Móstoles (Madrid), Spain c Institut für Anorganische Chemie der Universität Leipzig, Johannisallee 29, D-04103 Leipzig, Germany |
| Abstract: | The rac stereoisomer of a novel cryptand containing two bridgehead nitrogen and four asymmetric phosphorus atoms in the 16-membered core cycle was obtained stereoselectively via the reaction of bis(mesitylphosphino)propane, formaldehyde, and meta-xylylenediamine in the course of a covalent self-assembly process. |
| Keywords: | Phosphorus-containing cryptand Self-assembly Stereoselectivity True racemate |
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