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Alkoxide-induced nucleophilic trifluoromethylation using diethyl trifluoromethylphosphonate
Authors:Prabhakar Cherkupally
Affiliation:Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, Flemingovo nám 2, 166 10 Prague, Czech Republic
Abstract:A novel alkoxide-induced nucleophilic trifluoromethylation of carbonyl compounds, disulfides, and diselenides using diethyl trifluoromethylphosphonate is presented. In these reactions diethyl trifluoromethylphosphonate acts as a View the MathML source synthon.
Keywords:Trifluoromethylation   Phosphonate   Nucleophilic addition
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