Alkoxide-induced nucleophilic trifluoromethylation using diethyl trifluoromethylphosphonate |
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Authors: | Prabhakar Cherkupally |
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Affiliation: | Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, Flemingovo nám 2, 166 10 Prague, Czech Republic |
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Abstract: | A novel alkoxide-induced nucleophilic trifluoromethylation of carbonyl compounds, disulfides, and diselenides using diethyl trifluoromethylphosphonate is presented. In these reactions diethyl trifluoromethylphosphonate acts as a synthon. |
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Keywords: | Trifluoromethylation Phosphonate Nucleophilic addition |
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