Regioselective glycosylation of fully unprotected methyl hexopyranosides by means of transient masking of hydroxy groups with arylboronic acids |
| |
| Authors: | Eisuke Kaji Takashi Nishino Koji Ishige Yohei Ohya Yuko Shirai |
| |
| Institution: | School of Pharmacy, Kitasato University, Shirokane 5-9-1, Minato-ku, Tokyo 108-8641, Japan |
| |
| Abstract: | Facile, one-pot synthesis was developed for several β(1→2)-, β(1→3)- or β(1→4)-linked disaccharides from fully unprotected methyl hexopyranosides according to the molecular recognition by arylboronic acids. The methodology was successfully applied to facile, short step assembly of the trisaccharide fragment of type II arabinogalactan. |
| |
| Keywords: | Oligosaccharide Glycosylation Regioselectivity Masking Arylboronate |
| 本文献已被 ScienceDirect 等数据库收录！ |
