Chemoselective SN2′ reaction of nitroalkanes to dialkyl 2-(bromomethyl)fumarates under cetyltrimethylammonium hydroxide (CTAOH) catalysis |
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| Authors: | Roberto Ballini Serena Gabrielli Alessandro Palmieri |
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| Affiliation: | Green Chemistry Group, Dipartimento di Scienze Chimiche dell’Università di Camerino, Via S. Agostino 1, I-62032 Camerino (MC), Italy |
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| Abstract: | The chemoselective SN2′ reaction of a variety of primary nitroalkanes to dialkyl 2-(bromomethyl)fumarates can be efficiently performed under cetyltrimethylammonium hydroxide (CTAOH) catalysis. The α,β-unsaturated esters were obtained in satisfactory to good yields with the complete retention of the nitro group. |
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| Keywords: | Nitroalkanes CTAOH Chemoselective SN2&prime reaction α,β-Unsaturated esters γ-Lactame |
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