The first enantiospecific total synthesis of the 3-oxygenated sarpagine indole alkaloids affinine and 16-epiaffinine, as well as vobasinediol and 16-epivobasinediol |
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| Authors: | Jie Yang |
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| Affiliation: | Department of Chemistry, University of Wisconsin-Milwaukee, Milwaukee, WI 53211, USA |
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| Abstract: | The first enantiospecific total synthesis of the 3-oxygenated sarpagine indole alkaloids affinine (1) and 16-epiaffinine (2) as well as the synthesis of vobasinediol (3) and 16-epivobasinediol (4) was accomplished from d-(+)-tryptophan methyl ester. |
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