Novel method for the synthesis of functionalized tetrathiafulvalenes, an acceptor-donor-acceptor molecule comprising of two o-quinone moieties linked by a TTF bridge |
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| Authors: | Viacheslav Kuropatov Svetlana Klementieva Aleksander Mitin Yulia Budnikova Gleb Abakumov |
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| Affiliation: | a G.A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences, Tropinina str., 49, 603950, Nizhny Novgorod, Russian Federation
b A.E. Arbuzov Institute of Organic and Physical Chemistry of Russian Academy of Sciences, Arbuzov str. 8, Kazan, 420088 Russian Federation |
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| Abstract: | In search of a synthesis of o-quinone-tetrathiafulvalene-o-quinone triads a novel facile route was developed. Sodium tetrathiooxalate was for the first time used as a synthon in functionalized TTF preparation. The main purpose of this work was to construct an organic compound, which on the one hand possesses a redox-amphotericity, and on the other hand can act as a bridging ligand in construction of linear, 2D and 3D assemblies. Properties of new acceptor-donor-acceptor ligand in respect to application as a building block for the molecular devices have been investigated. |
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| Keywords: | o-Quinone Tetrathiafulvalene Tetrathiooxalate Acceptor-donor-acceptor triad |
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