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Ligand-free CuCl-catalyzed C-N bond formation in aqueous media |
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| Authors: | Hua-Jian Xu Fa-Yin Zheng Zhen-Ya Cai Da-Qing Che |
| Affiliation: | a School of Chemical Engineering, Hefei University of Technology, Hefei 230009, PR China b Anhui Key Laboratory of Controllable Chemical Reaction & Material Chemical Engineering, Hefei 230009, PR China c Zhejiang Jiuzhou Pharmaceutical Co., Ltd, Taizhou 318000, PR China |
| Abstract: | CuCl-catalyzed N-arylation of alkyl amines and N-heterocycles with substituted aryl iodides and bromides can be carried out in 40% nBu4N+OH− aqueous solution without any ligands. |
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