Direct substitution of propargylic alcohol with oxygen, nitrogen, and carbon nucleophiles catalyzed by molybdenum(VI) |
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| Authors: | Ming Zhang Yixiang Cheng |
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| Affiliation: | a State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China
b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China |
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| Abstract: | Efficient and direct substitution of propargylic alcohol with a variety of oxygen, nitrogen, and carbon nucleophiles catalyzed by MoO2(acac)2/NH4PF6 system was developed. The functional alkynes were obtained in modest to good yields with this versatile and practical protocol. |
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| Keywords: | Molybdenum Nucleophilic substitution Propargylation Alcohols |
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