Rate enhancement by water in a TiCl4-mediated stereoselective vinylogous Mukaiyama aldol reaction |
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| Authors: | Makoto Yamaoka |
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| Institution: | Faculty of Pharmaceutical Sciences, Tokyo University of Science (RIKADAI), 2641 Yamazaki, Noda-shi, Chiba 278-8510, Japan |
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| Abstract: | A remarkable enhancement in the rate of a TiCl4-mediated stereoselective vinylogous Mukaiyama aldol reaction (VMAR) using vinylketene silyl N,O-acetal 1 was observed in the presence of water. |
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| Keywords: | Vinylogous Mukaiyama aldol reaction Rate enhancement Water TiCl4-mediated reaction |
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