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Synthesis of polyphilic hexaazatrinaphthylenes and mesomorphic properties
Authors:Ming-Che Yeh
Affiliation:Department of Chemistry, National Sun Yat Sen University, Kaohsiung 804, Taiwan
Abstract:Methodologies for the synthesis of polyphilic hexaazatrinaphthylenes (HATN) with reduced symmetry based on the sequential condensation reactions of 1,2-bisalkoxy-4,5-diaminobenzenes with either tetrahydroxy-1,4-quinone or hexaketocyclohexane are described. The synthesized HATN possesses improved mesogenic properties and is liquid crystalline at room temperature.
Keywords:Sequential condensation   Hexaazatrinaphthylene   Difunctionalized   Mesogenic properties
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