Rhodium-catalyzed carbometalation of ynamides with organoboron reagents |
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| Authors: | Benoit Gourdet |
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| Affiliation: | School of Chemistry, University of Edinburgh, Joseph Black Building, The King’s Buildings, West Mains Road, Edinburgh EH9 3JJ, United Kingdom |
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| Abstract: | In the presence of catalytic [Rh(cod)(MeCN)2]BF4, ynamides undergo carbometalation with boronic acids, arylboronic esters, and triarylboroxines. These reactions enable the regio- and stereocontrolled synthesis of multisubstituted enamides. |
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