A non-classical hydrogen bond in the molybdenum arene complex [eta 6-C6H5C6H3(Ph)OH]Mo(PMe3)3: evidence that hydrogen bonding facilitates oxidative addition of the O-H bond |
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| Authors: | Hascall Tony Baik Mu-Hyun Bridgewater Brian M Shin Jun Ho Churchill David G Friesner Richard A Parkin Gerard |
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| Institution: | Department of Chemistry, Columbia University, New York, New York 10027, USA. |
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| Abstract: | Mo(PMe3)6 reacts with 2,6-Ph2C6H3OH to give the eta 6-arene complex eta 6-C6H5C6H3(Ph)OH]Mo(PMe3)3 which exhibits a non-classical Mo...H-OAr hydrogen bond; DFT calculations indicate that the hydrogen bonding interaction facilitates oxidative addition of the O-H bond to give eta 6,eta 1-C6H5C6H3(Ph)O]Mo(PMe3)2H. |
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