A novel organometallic columnar complex containing endohedral silver(I)-ethynediyl binding and exterior silver(I)-aromatic interaction |
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| Authors: | Wang Quan-Ming Mak Thomas C W |
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| Institution: | Department of Chemistry, Chinese University of Hong Kong, Shatin, New Territories, Hong Kong SAR, P. R. China. |
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| Abstract: | Unprecedented eta 3 pi-donor behavior of the benzyltrimethy-lammonium ion is observed in the polymeric silver(I) complex (PhCH2NMe3)Ag7(C2)(CF3CO2)6]n that comprises a columnar backbone constructed from the fusion of Ag8 square antiprisms each enclosing an acetylide dianion. |
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