A highly active Fe(I) catalyst for radical polymerisation and taming the polymerisation with iodine |
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| Authors: | Kamigaito Masami Onishi Isamu Kimura Shinichi Kotani Yuzo Sawamoto Mitsuo |
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| Affiliation: | Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 606-8501, Japan. |
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| Abstract: | A fast and controlled radical polymerisation of acrylates and acrylamides can be achieved with a combination of a highly active metal catalyst, Fe2Cp2(CO)4, and a mild radical scavenger, iodine, in the presence of an iodide initiator. |
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