Synthesis of hexagonal and cubic super-microporous niobium phosphates with anion exchange capacity and catalytic properties |
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Authors: | Mal Nawal Kishor Fujiwara Masahiro |
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Affiliation: | National Institute of Advanced Industrial Science and Technology (AIST), Kansai, 1-8-31 Midorigaoka, Ikeda, Osaka 563-8577, Japan. |
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Abstract: | Super-microporous hexagonal niobium phosphate synthesized using neutral surfactant (S0I0 mechanism) and cubic structure with cationic surfactant (S+X-I+); the hexagonal niobium phosphate possesses an excellent anion exchange capacity (6.3 mmol g-1) and high product selectivity towards 4-naphthaquinone (88.6%) in the oxidation of 1-naphthol in presence of aqueous H2O2. |
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