Eco-friendly fast synthesis and thermal degradation of optically active polyamides under microwave accelerating conditions |
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Authors: | Shadpour Mallakpour Mohammad Dinari |
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Institution: | Organic Polymer Chemistry Research Laboratory, Department of Chemistry, Isfahan University of Technology, Isfahan 84156-83111, I. R. Iran |
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Abstract: | An optically active bulky aromatic diacid chiral monomer, (2S)-4-(4-methyl-2-phthalimidylpentanoylamino) benzoylamino]isophthalic acid (1), containing a rigid phthalimide and flexible L-leucine pendent group was synthesized in five steps. A fast and clean method
for direct polyamidation reaction of monomer 1 with various aromatic diamines under microwave irradiation and conventional heating was performed. The polymerization reactions
provided optically active polyamides with high yields and inherent viscosities in the range of 0.36–0.74 dL/g. Their thermal
properties were evaluated by thermogravimetric analysis (TGA) and differential scanning calorimetry. TGA thermograms show
that the polymers are thermally stable, 10% weight loss temperatures are in excess of 385°C, and char yields at 800°C are
higher than 56%. The data obtained from TGA were used to study the kinetics of thermal decomposition of the resulting polymers.
The interpretation of kinetic parameters (E, ΔH, ΔS and ΔG) of thermal decomposition stages was evaluated using Coats and Redfern equation. |
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Keywords: | Optically active polyamides Amino acid Microwave irradiation Kinetic study Polycondensation |
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