首页 | 本学科首页   官方微博 | 高级检索  
     检索      


Eco-friendly fast synthesis and thermal degradation of optically active polyamides under microwave accelerating conditions
Authors:Shadpour Mallakpour  Mohammad Dinari
Institution:Organic Polymer Chemistry Research Laboratory, Department of Chemistry, Isfahan University of Technology, Isfahan 84156-83111, I. R. Iran
Abstract:An optically active bulky aromatic diacid chiral monomer, (2S)-4-(4-methyl-2-phthalimidylpentanoylamino) benzoylamino]isophthalic acid (1), containing a rigid phthalimide and flexible L-leucine pendent group was synthesized in five steps. A fast and clean method for direct polyamidation reaction of monomer 1 with various aromatic diamines under microwave irradiation and conventional heating was performed. The polymerization reactions provided optically active polyamides with high yields and inherent viscosities in the range of 0.36–0.74 dL/g. Their thermal properties were evaluated by thermogravimetric analysis (TGA) and differential scanning calorimetry. TGA thermograms show that the polymers are thermally stable, 10% weight loss temperatures are in excess of 385°C, and char yields at 800°C are higher than 56%. The data obtained from TGA were used to study the kinetics of thermal decomposition of the resulting polymers. The interpretation of kinetic parameters (E, ΔH, ΔS and ΔG) of thermal decomposition stages was evaluated using Coats and Redfern equation.
Keywords:Optically active polyamides  Amino acid  Microwave irradiation  Kinetic study  Polycondensation
本文献已被 CNKI 万方数据 SpringerLink 等数据库收录!
点击此处可从《高分子科学》浏览原始摘要信息
点击此处可从《高分子科学》下载免费的PDF全文
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号