Effect of the medium on the decomposition rate of di-t-butyl trioxide |
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| Authors: | A. F. Khalizov O. N. Makarova S. L. Khursan V. V. Shereshovets |
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| Affiliation: | (1) Institute of Organic Chemistry, Ural Department of the Russian Academy of Sciences, 450054 Ufa, Russia |
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| Abstract: | Using the chemiluminescence method, the effect of the medium on the overall rate constant of the thermal decomposition of di-tert-butyl trioxide has been studied. In all solvents investigated the decomposition occurs in accordance with a first order rate law. The effect of solvent on the rate constant (0°C) is analyzed. |
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