Bidentate amidine ligands for nickel(0)-mediated coupling of carbon dioxide with unsaturated hydrocarbons |
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| Authors: | Aoki Masao Kaneko Motomu Izumi Sawa Ukai Kazutoshi Iwasawa Nobuharu |
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| Affiliation: | Department of Chemistry, Tokyo Institute of Technology, Japan. |
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| Abstract: | Novel bidentate amidines were designed and synthesized as easily available electron-donating N-ligands for Ni0-mediated coupling of carbon dioxide with alkynes or allenes, and high regioselectivity was achieved even for the carboxylation of aryl substituted internal alkynes. |
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