Specific features of the thermodynamic equilibrium state of a thin water film in an electric field of surface active centers of a mica crystal

The structural features of a thin polar liquid film in an electric field of a charged substrate have been theoretically investigated using methods of statistical physics. It has been established that electrical interactions in this system lead to a change in the structure of the polar liquid and to the formation of clusters in it. A self-consistent nonlinear equation has been derived for describing the distribution of the potential and strength of the electric field inside the film under investigation. The depth of penetration of this field into the liquid medium has been studied as a function of the electrical activity of the substrate, temperature, degree of polarity of the liquid, and concentration of interface heterocharges. It has been revealed that the extent of structured regions in the liquid increases with an increase in the potential gradient of the internal field and with a decrease in the temperature.