Exclusive transition state stabilization in the supramolecular catalysis of Diels-Alder reaction by a uranyl salophen complex |
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| Authors: | Dalla Cort Antonella Mandolini Luigi Schiaffino Luca |
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| Affiliation: | Dipartimento di Chimica and IMC-CNR, Università La Sapienza, 00185 Roma, Italy. |
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| Abstract: | Whereas the parent uranyl salophen is catalytically inactive, its phenyl derivative effectively catalyses with turnover the reaction of benzoquinone with 1,3-cyclohexadiene, while showing no appreciable affinity towards reactants and product. |
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