Apparent molar volume,viscosity, and adiabatic compressibility of some mineral sulfates in aqueous binary mixtures of formamide at 298.15, 308.15, and 318.15 K |
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Authors: | M N Roy R Chanda B K Sarkar |
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Institution: | 1.Department of Chemistry,University of North Bengal,Darjeeling,India |
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Abstract: | The densities and viscosities of several sulfates, viz., ammonium sulfate, sodium sulfate, potassium sulfate, magnesium sulfate,
zinc sulfate and cadmium sulfate in aqueous binary mixtures of formamide (FA) have been determined at 298.15, 308.15, and
318.15 K and at atmospheric pressure. The ultrasonic speeds of the electrolytic solutions have also been measured at 298.15
K. Apparent molar volumes (ϕ
V
), viscosity B-coefficients and adiabatic compressibilities (K
S) of these electrolytic solutions were calculated from the experimental densitiy, viscosity and acoustic data. The density
and viscosity data were evaluated by using Masson’s and Jones-Dole equation respectively; the derived parameters have been
analyzed in terms of ion-ion and ion-solvent interactions. The structure making/breaking capacities of the electrolytes have
been inferred from the sign of (∂2ϕ
V
0/∂T
2)
P
. The results showed that all the electrolytes act as structure-makers in these media. Also the compressibility data indicated
electrostriction of the solvent molecules around the cations. The activation parameters of viscous flow were also determined
and discussed by the application of transition state theory. |
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Keywords: | |
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