(Liquid + liquid) equilibria in (water + ethanol + 2-ethyl-1-hexanol) at T=(298.2, 303.2, 308.2, and 313.2) K |
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Affiliation: | 1. Beykent University, Engineering and Architecture Faculty, Chemical Engineering Department, Ayazağa, İstanbul, Turkey;2. Malaviya National Institute of Technology (MNIT), Department of Chemical Engineering, Jaipur, Rajasthan, India;3. Chemical and Materials Engineering Department, Faculty of Engineering, King Abdulaziz University, P.O. Box 80204, Jeddah 21589, Saudi Arabia |
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Abstract: | (Liquid + liquid) equilibrium data for (water + ethanol + 2-ethyl-1-hexanol) were measured at atmospheric pressure in the temperature range (298.2 to 313.2) K. A type 1 (liquid + liquid) phase diagram was obtained for this ternary system. The experimental tie-line data for this system were correlated with the UNIQUAC solution model. The values of the interaction parameters between each pair of components in the system were obtained for the UNIQUAC model with the experimental results. The root mean square deviation between the observed and calculated mole per cent was 1.70%. The mutual solubility of 2-ethyl-1-hexanol and water was also investigated by the addition of ethanol at different temperatures. |
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