Gas-phase hydroformylation of propylene on Ru/SiO2 catalysts |
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| Authors: | S. B. Halligudi M. M. Taqui Khan B. L. Moroz A. L. Chuvilin I. P. Prosvirin V. A. Likholobov |
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| Affiliation: | (1) Central Salt and Marine Chemicals Research Institute, 364002 Bhavnagar, India;(2) Institute of Catalysis, 630090 Novosibirsk, USSR |
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| Abstract: | Ru/SiO2 catalysts prepared by reduction of supported RuCl3·xH2O are active in gas-phase hydroformylation of propylene at low pressure (ca. 0.3 MPa) of H2+CO+C3H6 mixtured and show unexpectedly high selectivity towards unbranched oxo-products. Data concerning the effect of electronic state and dispersity of Ru on their catalytic behavior have been obtained.
         Ru/SiO2,        RuCl3·xH2O,       ( 0,3   )       - .   .
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