Triflimide-catalyzed allyl-allyl cross-coupling: a metal-free allylic alkylation |
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| Authors: | Feiqing Ding Ronny William Fei Wang Xue-Wei Liu |
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| Institution: | Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 637371, Singapore. xuewei@ntu.edu.sg. |
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| Abstract: | A highly efficient metal-free intermolecular C(sp3)-C(sp3) allyl-allyl cross-coupling protocol between allyl acetates and allyltrimethylsilanes, which proceeded smoothly in the presence of catalytic triflimide to form 1,5-dienes with good to excellent regioselectivity, has been developed. |
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